材料科学
阳极
电化学
电解质
煅烧
阴极
碳纳米管
电池(电)
化学工程
电极
复合数
纳米线
碳纤维
铝
硒
电流密度
纳米技术
催化作用
复合材料
冶金
物理化学
有机化学
量子力学
物理
化学
功率(物理)
工程类
作者
Zhanyu Li,Jian Liu,Xiaogeng Huo,Jianling Li,Feiyu Kang
标识
DOI:10.1021/acsami.9b16597
摘要
Herein, we successfully prepared one-dimensional nanowire with carbon-coated selenium (Se@CW) by using a simple wet chemical method and obtained a one-dimensional hollow Se@C nanotube (Se@CT) after the subsequent calcination treatment. We have formed a new Al-Se secondary battery by using Se@CT as the cathode and metal aluminum as the anode in the AlCl3/[EMIm]Cl electrolyte. It is believed that the oxidation intermediate of Se in Al-Se batteries may not only have Se22+, but there may be other oxidation intermediates, such as Se4+, Se2+, and Se82+. Therefore, Se@CT exhibits excellent charge–discharge performance in Al-Se batteries. Its initial discharge capacity reaches 447.2 mA h g–1 at 200 mA g–1, and the operating voltage is above 1.6 V. Its energy density approaches 708.8 W h k g–1, the capacity is still 162.9 mA h g–1 after 200 cycles at 500 mA g–1, and the corresponding capacity retention rate is up to 83.5%. In addition, its electrochemical performance is far superior to that of Se@CMK-3 in Al-Se batteries and the electrochemical properties of carbon materials, oxides, and sulfide electrode materials in some aluminum-ion batteries, which will open up a new direction for the development of new secondary aluminum-based batteries.
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