In this paper we report on the thermoluminescence of Cs 2 LiYCI 6 , Cs 2 LiYCl 6 :Ce 3+ and Cs 2 LiYCl 6 :Pr 3+ crystals. Low-temperature glow curves and isothermal decay spectra are presented. All three crystals exhibit prominent glow peaks below 300 K. The Cs 2 LiYCl 6 sample shows a major peak at 58 K in addition to a broad band between 75 K and 150 K. The glow curve of Cs 2 LiYCl 6 :Pr 3+ is similar to that of Cs 2 LiYCl 6 but shows additional peaks at 222 K and 277 K. The glow curve of Cs 2 LiYCl 6 :Ce 3+ is dominated by a major glow peak at 214 K with minor peaks at 50 K and 88 K. Lifetimes of traps derived from isothermal decay spectra measured at the temperature maximum of selected glow peaks are of the order of tens of seconds.