A metallic gas diffusion layer and porous media flow field for proton exchange membrane fuel cells

质子交换膜燃料电池 阴极 材料科学 多孔介质 金属泡沫 化学工程 微型多孔材料 化学计量学 扩散 多孔性 复合材料 气体扩散 化学 电极 热力学 有机化学 生物化学 物理 工程类 物理化学
作者
Ying‐Hui Zhang,Youkun Tao,Hongliang Ren,Minhua Wu,Guanguang Li,Zhijian Wan,Jing Shao
出处
期刊:Journal of Power Sources [Elsevier BV]
卷期号:543: 231847-231847 被引量:15
标识
DOI:10.1016/j.jpowsour.2022.231847
摘要

Recently, metal foams have been intensively studied to be used as alternative flow fields to the conventional channel-rib flow field in proton exchange membrane fuel cells (PEMFC) to enhance the uniformity of gas distribution and reduce the weight of fuel cells. This work demonstrates a simple and compact design at the cathode side for achieving effective electrons and gas transport in PEMFCs, which includes a porous metal foam flow media coated with a microporous layer (MPL) on its top to form one single hierarchical porous component functioning as both the gas distributor and diffusion media. With this low-cost and light-weight design, the conventional gas diffusion layer (GDL) can be eliminated. A comparative analysis of PEM fuel cell performances for the conventional carbon paper-based GDL and three metallic GDL designs containing different MPLs is conducted under varied stoichiometric ratios and relative humidity (RH). At 100% RH, the optimum performance is achieved on the CB/CNT MPL-coated metal foam, with the maximum power density increased by 21% than that of the conventional design when the stoichiometric ratio of air is 1.5. Under dry conditions (40% RH), all the metallic GDL structured cells outperform the conventional one at a low airflow rate (stoichiometric ratio = 1.5). • A metallic GDL with Ni foam flow field design at the cathode is developed. • The novel design outperforms the design with a conventional GDL at high humidity. • The MPL on the Ni foam can greatly affect the conductivity and mass transfer. • The CB/CNT MPL improves the electron, oxygen and water transport at high humidity. • The metal foam with a GR MPL exhibits a higher water retention capability.
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