质子交换膜燃料电池
阴极
材料科学
多孔介质
金属泡沫
化学工程
微型多孔材料
化学计量学
扩散
多孔性
复合材料
气体扩散
化学
膜
电极
热力学
有机化学
生物化学
物理
工程类
物理化学
作者
Ying‐Hui Zhang,Youkun Tao,Hongliang Ren,Minhua Wu,Guanguang Li,Zhijian Wan,Jing Shao
标识
DOI:10.1016/j.jpowsour.2022.231847
摘要
Recently, metal foams have been intensively studied to be used as alternative flow fields to the conventional channel-rib flow field in proton exchange membrane fuel cells (PEMFC) to enhance the uniformity of gas distribution and reduce the weight of fuel cells. This work demonstrates a simple and compact design at the cathode side for achieving effective electrons and gas transport in PEMFCs, which includes a porous metal foam flow media coated with a microporous layer (MPL) on its top to form one single hierarchical porous component functioning as both the gas distributor and diffusion media. With this low-cost and light-weight design, the conventional gas diffusion layer (GDL) can be eliminated. A comparative analysis of PEM fuel cell performances for the conventional carbon paper-based GDL and three metallic GDL designs containing different MPLs is conducted under varied stoichiometric ratios and relative humidity (RH). At 100% RH, the optimum performance is achieved on the CB/CNT MPL-coated metal foam, with the maximum power density increased by 21% than that of the conventional design when the stoichiometric ratio of air is 1.5. Under dry conditions (40% RH), all the metallic GDL structured cells outperform the conventional one at a low airflow rate (stoichiometric ratio = 1.5). • A metallic GDL with Ni foam flow field design at the cathode is developed. • The novel design outperforms the design with a conventional GDL at high humidity. • The MPL on the Ni foam can greatly affect the conductivity and mass transfer. • The CB/CNT MPL improves the electron, oxygen and water transport at high humidity. • The metal foam with a GR MPL exhibits a higher water retention capability.
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