Effect of space UV irradiation on the mechanical and tribological properties of Cr and B doped hydrogen-containing diamond-like films

To promote the wide application of hydrogen-containing diamond-like films (a-C:H) as solid lubricant materials in aerospace environment, a series of a-C:H, a-C:H doped with Cr elements (Cr/a-C:H) and a-C:H doped with B elements (B/a-C:H) were prepared on the GCr15 steel by non-equilibrium magnetron sputtering technique. The effects of ultraviolet (UV) irradiation on the mechanical and tribological properties of the three DLC films were investigated. UV irradiation was found to cause a decline in hardness and modulus of elasticity, and increased residual stress and surface roughness in all three films. UV irradiation has a minor impact to the coefficient of friction of the three films, but leads to a decrease in wear life. The wear life of Cr/a-C:H films was least affected by UV irradiation. UV irradiation can lead to the breakage of sp3C-H bonds in a-C:H film and B/a-C:H film, resulting in the increase of dangling bonds in the films and the decrease of wear life. In the Cr/a-C:H film, the broken sp3 C-H bond is partially reorganized into sp2 C-H bond, which further exerts the passivation effect of C-H bond, resulting in a smaller decrease in the wear life of the Cr/a-C:H film.