加氢脱氧
催化作用
除氧
粒径
氢解
粒度
粒子(生态学)
化学
化学工程
纳米颗粒
分析化学(期刊)
材料科学
纳米技术
物理化学
有机化学
冶金
选择性
海洋学
工程类
地质学
作者
Camila A. Teles,Carmen Ciotonea,Anthony Le Valant,Christine Canaff,Jérémy Dhainaut,Jean‐Marc Clacens,Fábio B. Noronha,Frédéric Richard,Sébastien Royer
标识
DOI:10.1016/j.apcatb.2023.123030
摘要
By taking advantage of different nanoparticle size control methodologies, the precise role of Ni particle size (from 1 nm to 9 nm) was evaluated in the HDO of m-cresol in vapor phase at 573 K under atmospheric pressure. The m-cresol HDO reaction pathways were found to be Ni-particle size dependent. The direct deoxygenation (DDO) rate increased by 10 times when decreasing Ni particle size from 9 nm to 1 nm, while the hydrogenation (HYD) and hydrogenolysis (HYG) rates moderately increased. By applying a geometric model, reaction rates were correlated to the different type of sites. Edges and corner sites (smaller particles) favor aromatics production (DDO route), while face sites (larger particles) favor both HYD and HYG routes. Catalysts partially deactivated due to coke formation, with only slight sintering observed for 1 nm Ni particles. Such findings may serve in the further preparation of active and selective catalysts for bio-oils upgrading into fuel.
科研通智能强力驱动
Strongly Powered by AbleSci AI