化学
电化学
有机合成
阴极保护
羟基化
有机溶剂
绿色化学
水介质
水溶液
电解质
支撑电解质
有机化学
无机化学
催化作用
化学工程
电极
物理化学
工程类
酶
标识
DOI:10.1002/ijch.202300067
摘要
Abstract Conducting electrochemical organic synthesis in/on whole water media is undoubtedly a highly green approach, which avoids the usage of organic solvents, and sometimes organic supporting electrolytes. In this review, the electrochemical organic syntheses in/on whole water environment are reviewed, especially including the reactions conducted both in organic solvent and water for comparisons. This review discussed anodic and cathodic reaction, respectively, including the C−H oxidation, hydroxylation, dehydrogenative cross coupling, functionalization of alkenes, cathodic oxidation, hydrogenation, reductive cross coupling, and so on. As the reduction of CO 2 , conversion biomass, and waste water disposal are frequently performed in water, and have already been reviewed recently. These topics are not included in this review.
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