材料科学
混溶性
能量转换效率
结晶度
接受者
聚合物
电子受体
兴奋剂
聚合物太阳能电池
结晶
化学工程
氟
电子供体
活动层
图层(电子)
有机太阳能电池
光电子学
纳米技术
光化学
有机化学
化学
复合材料
物理
催化作用
薄膜晶体管
工程类
冶金
凝聚态物理
作者
Donghua Zhou,Chentong Liao,Shaoqian Peng,Xiaopeng Xu,Yuanyuan Guo,Jianlong Xia,Huifeng Meng,Liyang Yu,Ruipeng Li,Qiang Peng
标识
DOI:10.1002/advs.202202022
摘要
Despite remarkable breakthrough made by virtue of "polymerized small-molecule acceptor (PSMA)" strategy recently, the limited selection pool of high-performance polymer acceptors and long-standing challenge in morphology control impede their further developments. Herein, three PSMAs of PYDT-2F, PYDT-3F, and PYDT-4F are developed by introducing different fluorine atoms on the end groups and/or bithiophene spacers to fine-tune their optoelectronic properties for high-performance PSMAs. The PSMAs exhibit narrow bandgap and energy levels that match well with PM6 donor. The fluorination promotes the crystallization of the polymer chain for enhanced electron mobility, which is further improved by following n-doping with benzyl viologen additive. Moreover, the miscibility is also improved by introducing more fluorine atoms, which promotes the intermixing with PM6 donor. Among them, PYDT-3F exhibits well-balanced high crystallinity and miscibility with PM6 donor; thus, the layer-by-layer processed PM6/PYDT-3F film obtains an optimal nanofibril morphology with submicron length and ≈23 nm width of fibrils, facilitating the charge separation and transport. The resulting PM6/PYDT-3F devices realizes a record high power conversion efficiency (PCE) of 17.41% and fill factor of 77.01%, higher than the PM6/PYDT-2F (PCE = 16.25%) and PM6/PYDT-4F (PCE = 16.77%) devices.
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