化学
齿合度
杂原子
锰
特里斯
金属
立体化学
衍生工具(金融)
氧原子
药物化学
分子
有机化学
戒指(化学)
生物化学
金融经济学
经济
作者
Pierre R. Marcoux,Bernold Hasenknopf,Jacqueline Vaissermann,Pierre Gouzerh
标识
DOI:10.1002/ejic.200200677
摘要
Abstract Anderson‐type polyoxomolybdates [MMo 6 O 18 {(OCH 2 ) 3 CNH 2 } 2 ] 3− (M = Mn III , Fe III ) were prepared and structurally characterized. The tris(alkoxo) ligands are bound to the central heteroatom via their oxygen atoms. The corresponding compounds with M = Ni II or Zn II are not accessible since these cations have a preference for the amino functionality. The pendant amino groups of the manganese‐containing derivative react with pyridinecarbaldehydes to give the corresponding imines. This provides new mono‐ and bidentate binding sites for metal cations. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
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