材料科学
钙钛矿(结构)
能量转换效率
带隙
兴奋剂
掺杂剂
锂(药物)
氟化锂
介电谱
串联
化学工程
粒度
纳米技术
无机化学
光电子学
电化学
电极
化学
复合材料
物理化学
内分泌学
工程类
医学
作者
Jin Huang,Kewang Shi,Chunyang Chen,Hao Wang,Shengzhong Liu
标识
DOI:10.1002/ente.202201242
摘要
All‐inorganic CsPbI 3 perovskite is an ideal solar material with an appropriate bandgap (≈1.73 eV) that can be used for the top cell in tandem cells matched to crystalline silicon or low‐bandgap perovskites. Efficient all‐inorganic perovskite solar cells (PSCs) provide the cornerstone for efficient tandem cells. However, all‐inorganic PSCs are less efficient than organic–inorganic hybrids PSCs, and because CsPbI 3 is incompatible with water, the stability of perovskite must be improved. Herein, a novel method for preparing efficient and stable PSCs via ionic chemical doping is proposed. Lithium fluoride as an inorganic ionic dopant can control grain growth and get larger grain sizes. The crystal structure, morphology, and electrochemical impedance spectroscopy of LiF‐doped all‐inorganic perovskite films are studied to determine the relationship between film quality and device performance. The doping of 2 mol% LiF considerably enhances the performance of the device, eliminates the hysteresis effect of the device, and the maximum power conversion efficiency of PSCs is raised to 17.02%. Additionally, device stability is greatly enhanced.
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