A nano rod-like α-MnO2 supported on carbon nanotubes modified separator inhibiting polysulfide shuttle in Li-S batteries

Lithium-sulfur (Li-S) batteries have attracted enormous attentions as new-generation energy storage devices due to their high theoretical energy density, high theoretical specific capacity, low cost and environmental friendliness. However, polysulfide shuttle and the growth of lithium dendrites significantly restrain the practical application of the Li-S batteries. In this work, a modified PP separator with nanoscale rod-like α-MnO 2 supported on carbon nanotubes was prepared. The α-MnO 2 @CNT modified separator can effectively inhibit the shuttle of polysulfide, enhance the electrochemical activity and accelerate the transfer of ions and electrons. The density functional theory (DFT) calculations demonstrate that α-MnO 2 @CNT can efficiently adsorb and catalyze the conversion of polysulfides. Due to these advantages, the α-MnO 2 @CNT-based Li-S battery delivers a initial discharge capacity of 1469 mAh g -1 at 0.05 C, 1039 mAh g -1 at 0.5 C and the capacity can still maintain 648 mAh g -1 over 500 cycles at 0.5 C (capacity decay rate of 0.075%). Expressly, the capacity decay rate is only 0.022% after 600 cycles at a high current density of 2 C. The excellent performance could be attributed to the α-MnO 2 @CNT modified separator not only accelerating the transmission of electrons but also effectively inhibiting the shuttle of polysulfides. Moreover, this work provides a better idea for practical applications of lithium-sulfur batteries in the future. A nano rod-like α-MnO 2 supported on CNT composite possess good conductivity network and excellent adsorption ability. Therefore, the α-MnO 2 @CNT modified separator provides a polysulfide adsorption site, effectively inhibits the shuttle of polysulfide, and accelerates the catalytic transformation and kinetic behavior of polysulfide. As a result, the α-MnO 2 @CNT modified separator battery achieves good electrochemical performance and high discharge specific capacity. • The synthesized α-MnO 2 is in the shape of nanorods. • The α-MnO 2 @CNT composite has good polysulfide adsorption and catalytic conversion ability. • The α-MnO 2 @CNT modified separator shows an excellent long-term cycling stability and rate performance.