Pure organic: The synthesis of tetrasubstituted furans often involves transition-metal catalysis or metal–halogen exchange reactions. A new approach to these heterocycles employs the Feist–Bénary addition–elimination process using nitroallylic acetates and 1,3-dicarbonyls (see scheme; X=C, O). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.