二聚体
化学
菲咯啉
螯合作用
结晶学
钆
离子
立体化学
无机化学
有机化学
作者
Shoubin Wang,Hongmei He,Sheng Li,Kun Tang
标识
DOI:10.1107/s1600536808004431
摘要
In the title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(12)H(8)N(2))(2)], the asymmetric unit comprises one Gd(3+) cation chelated by two 2,4-difluoro-benzoate and one 1,10-phenanthroline ligands. Two cations are linked into a centrosymmetric dimer via three bridging carboxyl-ate groups of 2,4-difluoro-benzoate ligands. Each Gd(3+) ion is nine-coordinated by seven O atoms and two N atoms.
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