多面体
化学
金属有机骨架
维数之咒
拓扑(电路)
顶点(图论)
多孔性
晶体结构
网状结缔组织
多样性(控制论)
结晶学
纳米技术
几何学
组合数学
有机化学
计算机科学
材料科学
理论计算机科学
吸附
人工智能
病理
图形
机器学习
数学
医学
作者
Hiroyasu Furukawa,Jaheon Kim,Nathan W. Ockwig,Michael O’Keeffe,Omar M. Yaghi
摘要
Metal−organic polyhedra and frameworks (MOPs and MOFs) were prepared by linking square units M2(CO2)4 (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and crystal structures of 5 new MOPs and 11 new MOFs (termed MOP-14, -15, -17, -23, -24 and MOF-114, -115, -116, -117, -118, -119, -222, -601, -602, -603, -604) and show how their structures are related to the shape and functionality of the building blocks. The gas uptake behaviors of MOP-23 and MOF-601 to -603 are also presented as evidence that these structures have permanent porosity and rigid architectures.
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