Confined Bismuth–Organic Framework Anode for High‐Energy Potassium‐Ion Batteries

Metal-organic frameworks (MOFs) with inherent porosity, controllable structures, and designable components are recognized as attractive platforms for designing advanced electrodes of high-performance potassium-ion batteries (PIBs). However, the poor electrical conductivity and low theoretical capacity of many MOFs lead to inferior electrochemical performance. Herein, for the first time, a confined bismuth-organic framework with 3D porous matrix structure (Bi-MOF) as anode for PIBs via a facile wet-chemical approach is reported. Such a porous structure design with double active centers can simultaneously ensure the structure integrity and efficient charge transport to enable high-capacity electrode with super cycling life. As a result, the Bi-MOF for PIBs exhibits high reversible capacity (419 mAh g^-1 at 0.1 A g^-1 ), outstanding cycling stability (315 mAh g^-1 at 0.5 A g^-1 after 1200 cycles), and excellent full battery performance (a high energy density of 183 Wh kg^-1 is achieved, outperforming all reported metal-based anodes for PIBs). Moreover, the K⁺ storage mechanisms of the Bi-MOF are further unveiled by in situ Raman, ex situ high-resolution transmission electron microscopy, and ex situ Fourier-transform infrared spectroscopy. This ingenious electrode design may provide further guidance for the application of MOF in energy storage systems.