Robust Silica-Cellulose Composite Aerogels with a Nanoscale Interpenetrating Network Structure Prepared Using a Streamlined Process

Silica aerogels can be strengthened by forming a nanoscale interpenetrating network (IPN) comprising a silica gel skeleton and a cellulose nanofiber network. Previous studies have demonstrated the effectiveness of this method for improving the mechanical properties and drying of aerogels. However, the preparation process is generally tedious and time-consuming. This study aims to streamline the preparation process of these composite aerogels. Silica alcosols were directly diffused into cellulose wet gels with loose, web-like microstructures, and an IPN structure was gradually formed by regulating the gelation rate. Supercritical CO₂ drying followed to obtain composite aerogels. The mechanical properties were further enhanced by a simple secondary regulation process that increased the quantity of bacterial cellulose (BC) nanofibers per unit volume of the matrix. This led to the production of aerogels with excellent bendability and a high tensile strength. A maximum breaking stress and tensile modulus of 3.06 MPa and 46.07 MPa, respectively, were achieved. This method can be implemented to produce robust and bendable silica-based composite aerogels (CAs).