荧光
光化学
喹啉
罗丹明
化学
罗丹明B
水溶液中的金属离子
紫外线
吸收带
吸收(声学)
离子
检出限
肉眼
吸收光谱法
材料科学
有机化学
光催化
催化作用
光电子学
光学
复合材料
物理
量子力学
作者
Huie Jiang,Danni Tang,Nihao Li,Junwei Li,Li Z,Qingxin Han,Xinhua Liu,Xia Zhu
标识
DOI:10.1016/j.saa.2020.119365
摘要
• A novel dual-functional chemosensor was developed to detect Cu 2+ and Hg 2+ . • Cu 2+ facilitated the opening of its rhodamine spirocycle. • Hg 2+ activated the opening of the rhodamine spirocycle and formed a new cycle. • Cu 2+ and Hg 2+ were detected by off–on fluorescence and ratiometric UV–Vis. • The chemosensor with low cytotoxicity could be successfully monitored Cu 2+ and Hg 2+ in living cells. A novel dual-functional chemosensor, derived from the conjugation of rhodamine B with a quinoline derivative (RHQ), was firstly synthesized with high efficiency and cost-effectiveness for the distinguishable detections of Cu 2+ and Hg 2+ via ring-opening and ring-forming mechanism. The chemosensor exhibits highly selective and distinguishable responses for Cu 2+ and Hg 2+ in CH 3 CN–H 2 O (4:1, v/v) with off–on fluorescence and ratiometric ultraviolet–visible (UV–Vis) absorption changes. Additionally, Cu 2+ is identified by opening a rhodamine spirocycle with a UV–Vis absorption band, at around 560 nm and fluorescence turn-on. Interestingly, Hg 2+ is discerned by opening the rhodamine spirocycle and by generating a new special cycle for the quinoline unit. Resultantly, there were two UV–Vis absorption bands at around 365 nm and 560 nm, which were accompanied by fluorescence turn-on. Moreover, the chemosensor can quantitatively detect Cu 2+ and Hg 2+ by off–on fluorescence and ratiometric UV–Vis absorption changes, respectively. Furthermore, the chemosensor with low cytotoxicity could be successfully administered to monitor Cu 2+ and Hg 2+ in living cells. This work may pay the way for the development of dual-functional chemosensor for quantificationally detecting metal ions in environmental and biological systems.
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