石墨烯
材料科学
电化学
催化作用
杂原子
电催化剂
X射线光电子能谱
分解水
剥脱关节
插层(化学)
化学工程
碳纤维
氢
金属
共价键
纳米技术
无机化学
化学
复合数
复合材料
电极
有机化学
物理化学
冶金
光催化
工程类
戒指(化学)
作者
Mehmet Giray Ersözoğlu,Hürmüs Gürsu,Selin Gümrükçü,A. Sezai̇ Sarac,Yücel Şahin
标识
DOI:10.1002/celc.202101455
摘要
Abstract The hydrogen evolution reaction (HER) is the core of electrocatalysis and plays a crucial role in water splitting to obtain hydrogen. It has been inevitable to develop metal‐free catalysts in terms of sustainability, the environment, and economic feasibility. Carbon‐based materials are called metal‐free electrocatalysts and are regarded as one of the most promising candidates due to their abundant source, but they often show poor activity. The strategic aim of this study is to convert commercial carbon fiber into heteroatom‐doped graphene‐like surfaced fibers via an eco‐friendly and fast intercalation/semi‐exfoliation mechanism called Yucel's method. Furthermore, X‐ray photoelectron spectroscopy (XPS) verified that the intercalation has successfully taken place and that the heteroatoms (S, O) are connected to the graphene‐like structure by covalent bonds. The catalysts with 1 M H 2 SO 4 showed superior HER performance compared to bare CF.
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