Effect of Slag Basicity on Non-Metallic Inclusions and Cleanliness of 15-5PH Stainless Steel

Few reports exist on the effect of the basicity of refining slag on inclusions in 15-5PH stainless steel and its removal efficiency. In this study, the effects of various basicities on the formation and removal efficiency of inclusions in molten steel were investigated. To investigate the effect of the chemical makeup of slag on the non-metallic inclusions in liquid steel, laboratory experiments and thermodynamic calculations were conducted on CaO-MgO-SiO2-Al2O3-CaF2 slag with various slag basicities and 15-5PH stainless steel. In the steel samples that had reacted with high-basicity slag samples, the magnesium content and aluminum yield were higher. Thermodynamic findings according to the ion and molecule coexistence theory showed that log (aSiO23/aAl2O32) decreases as slag basicity increases. This increases the Al concentration in liquid steel while decreasing the Si content. Log (aMgO3/aAl2O3) also increases, increasing the Mg content of the molten steel. With this, the transformation order of oxide inclusions is Al2O3 → MgAl2O4 → MgO. High-basicity slag increases the attachment of slag to inclusions and generates MgAl2O4 inclusions that are more easily adsorbed by inclusions in molten steel, thereby improving the cleanliness of molten steel.