等结构
氨
检出限
化学
相对湿度
发光
湿度
镧系元素
光致发光
重复性
分析化学(期刊)
风化
晶体结构
材料科学
矿物学
热力学
有机化学
色谱法
离子
光电子学
物理
作者
Supaphorn Thammakan,Malee Sinchow,Natthiti Chiangraeng,Nobuto Yoshinari,Takumi Konno,Athipong Ngamjarurojana,Piyarat Nimmanpipug,Apinpus Rujiwatra
标识
DOI:10.1021/acs.cgd.3c00680
摘要
Aiming at ammonia gas detection at ambient temperature, phenoxyacetic acid (Hpoa) and 2,5-pyridinedicarboxylic acid (H2pydc) were employed to construct the isostructural [LnIII(poa)(2,5-pydc)(H2O)2]·3H2O (LnIII = EuIII (I), GdIII (II), and TbIII (III)). Their single crystal structures and photophysical properties as well as the triplet state energies of the sensitizers were characterized. Robustness and responses of I and its composite film with poly(vinyl alcohol) (I/PVA) toward water, ammonia, and common volatile organic compounds were examined. The substantial quenching of EuIII:5D0 → 7FJ by only ammonia was disclosed, and the underlying mechanism was postulated based on experimental and computational studies. Referring to EuIII:5D0 → 7F2, the response R parameter was defined. Under ambient temperature (25–35 °C) and humidity (45–55% RH), a linear dependence of R on ammonia concentration (0.50–10.0 ppm) was obtained from I/PVA. Based on the calibration method, the sensitivity (4.04%·ppm–1), detection limit (0.14 ppm), percentage recoveries (103–111% for 3.50, 6.50, and 8.50 ppm), and relative standard deviation (1.5–8.2%) were determined. The reuse of the film for at least 10 cycles was demonstrated with 95–97% repeatability. Limitation of the detection by extreme humidity was presented.
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