咪唑酯
催化作用
材料科学
沸石咪唑盐骨架
纳米片
活动站点
化学工程
碳纤维
兴奋剂
再分配(选举)
纳米技术
氧气
多孔性
无机化学
金属有机骨架
化学
有机化学
吸附
光电子学
政治
复合数
政治学
法学
工程类
复合材料
作者
Shaojun Jiang,Guanying Ye,Weiwei Zhu,Suqin Liu,Zhen He,Guanhua Jin
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2023-11-17
卷期号:11 (48): 16926-16934
标识
DOI:10.1021/acssuschemeng.3c04125
摘要
Defect and morphology engineering of metal-nitrogen codoped carbon (M-N/C) has been proven to be efficacious in promoting the oxygen reduction reaction (ORR) catalytic activity, yet the simultaneous construction of active sites with high intrinsic activity and efficient exposure is a challenge. Herein, an Fe-N/C catalyst consisting of edge Fe-N4 sites atomically dispersed on porous carbon nanosheets (e-Fe-N/CNS) is designed for high intrinsic catalytic active as well as efficient utilization. By combining an edge-doping process and an I2-etching effect, the edge Fe-N4 sites are constructed preferentially and the interior active sites are fully exposed. The edge Fe-N4 sites endow e-Fe-N/CNS with high intrinsic activity, which originated from the local electronic redistribution of the Fe-N4 configuration induced by the edge carbon, while the enriched porous nanosheet structure enhances the edge Fe-N4 sites utilization efficiency for high mass activity. The as-synthesized e-Fe-N/CNS exhibits a remarkable half-wave potential (E1/2, 0.90 VRHE) under alkaline conditions. This work provides a novel synthetic method for designing highly active defective sites in catalysts for energy conversion systems.
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