光催化
异质结
纳米笼
化学
化学工程
碳纤维
热解
纳米技术
催化作用
材料科学
光电子学
有机化学
复合数
工程类
复合材料
作者
Ke Yi,Qian Liang,Shuang Zhao,Zhi‐Hui Zhang,Xiazhang Li,Zhongyu Li
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2022-01-26
卷期号:61 (5): 2652-2661
被引量:32
标识
DOI:10.1021/acs.inorgchem.1c03778
摘要
Photocatalytic CO2 reduction to carbon fuels is regarded as an ideal and sustainable way to provide clean energy and solve environmental crisis. Herein, a p-n Co3O4/TiO2 heterojunction photocatalyst was synthesized by one-step pyrolysis of self-assembly ZIF-67/MIL-125, which was used in photocatalytic CO2 reduction for the first time. Co3O4 nanocages were highly dispersed on the surface of TiO2 nanoplates with an intimate contact. The optimal Co3O4/TiO2 exhibited a significantly enhanced CO evolution rate of 1256 μmol g-1 h-1 under simulated solar light, which was 2.4 times higher than that of pure Co3O4. The high photocatalytic performance of Co3O4/TiO2 was attributed to its enriched active sites and formed p-n heterojunctions. According to the electrocatalytic measurements, the possible mechanism and photoinduced charge transfer process were discussed in detail. We believe that this research provides a facile and efficient approach to fabricate MOF-derived heterojunction photocatalysts for CO2 reduction.
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