Electric Field Regulator Constructed by Magnetron Sputtering for Dendrite‐Free and Stable Zinc Metal Anode

Abstract Rechargeable aqueous zinc‐ion batteries (AZIBs) are considered to be one of the most promising devices in the next generation of energy storage systems. However, the uncontrolled growth of Zn dendrites during electroplating leads to rapid battery failure, which hinders the wide application of AZIBs. In this work, an Fe metal interface (FMI) with electric field regulation is designed on the Zn metal anode using a magnetron sputtering technology. The FMI layer with nanosheet array not only uniforms the surface electric field, but also adjusts the surface Zn 2+ ion distribution to inhibit 2D diffusion. The strong orientation relationships of the FMI layer enhance the reversibility of Zn plating/stripping, improving the structural stability of the interface layer. Consequently, FMI@Zn symmetric cell exhibits ultra‐stable lifespan for over 6000 h (Cumulative plated capacity, CPC = 15 Ah cm −2 ) with a low voltage hysteresis of 46.4 mV and high Coulombic efficiency of 99.8% at 5 mA cm −2 . Even at the large current density of 40 mA cm −2 , the CPC reaches 19.7 Ah cm −2 . The proposed electric field regulation strategy reveals a promising prospect for designing highly stable Zn anode, which also applies to other metal anodes in energy storage systems.