质子交换膜燃料电池
气体扩散
水运
毛细管作用
热扩散率
电解质
磁导率
相对渗透率
扩散
化学
材料科学
燃料电池
化学工程
分析化学(期刊)
膜
热力学
水流
复合材料
色谱法
环境科学
多孔性
环境工程
工程类
物理
生物化学
物理化学
电极
作者
Yulin Wang,Shixue Wang,Wenzhe Yang,Guozhuo Wang
标识
DOI:10.1016/j.egypro.2019.01.270
摘要
Fundamental understanding of the transport properties in gas diffusion layers (GDLs) is a critical issue for the optimal design of polymer electrolyte membrane (PEM) fuel cell. The utilization of the Bruggeman correlation, the Leverett-J function and the Wyllie's model in the description of the gaseous effective diffusivity, capillary characteristics and liquid water relative permeability in GDLs has been doubted in accurately estimating the effective diffusivities of the GDLs. In this study, a three-dimensional, two-phase flow PEM fuel cell model was developed to investigate how this inaccuracy is reflected on the fuel cell performance. The numerical results show that the gas diffusion and liquid water transport in GDLs are strongly determined by the effective diffusivities, which are closely correlated with the cell performance. The gas diffusion exhibits a more significant effect on the cell performance than the liquid water transport and water relative permeability. The water relative permeability is the dominant factor in determining the liquid water transport compared with the capillary characteristics.
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