Metal–Organic Frameworks‐Derived Mesoporous Si/SiOx@NC Nanospheres as a Long‐Lifespan Anode Material for Lithium‐Ion Batteries

Silicon (Si)-based anode materials with suitable engineered nanostructures generally have improved lithium storage capabilities, which provide great promise for the electrochemical performance in lithium-ion batteries (LIBs). Herein, a metal-organic framework (MOF)-derived unique core-shell Si/SiO_x @NC structure has been synthesized by a facile magnesio-thermic reduction, in which the Si and SiO_x matrix were encapsulated by nitrogen (N)-doped carbon. Importantly, the well-designed nanostructure has enough space to accommodate the volume change during the lithiation/delithiation process. The conductive porous N-doped carbon was optimized through direct carbonization and reduction of SiO₂ into Si/SiO_x simultaneously. Benefiting from the core-shell structure, the synthesized product exhibited enhanced electrochemical performance as an anode material in LIBs. Particularly, the Si/SiO_x @NC-650 anode showed the best reversible capacities up to 724 and 702 mAh g^-1 even after 100 cycles. The excellent cycling stability of Si/SiO_x @NC-650 may be attributed to the core-shell structure as well as the synergistic effect between the Si/SiO_x and MOF-derived N-doped carbon.