化学
单线态氧
过氧化氢
光化学
歧化
微乳液
发光
钼酸盐
氧气
过氧化物
光氧化
催化作用
有机化学
肺表面活性物质
生物化学
光电子学
物理
作者
Véronique Nardello,S.C.G. Van den Bogaert,Paul L. Alsters,Jean‐Marie Aubry
标识
DOI:10.1016/s0040-4039(02)02108-1
摘要
Seventeen organic solvents are screened as reaction media to conduct the molybdate-catalyzed disproportionation of hydrogen peroxide into singlet molecular oxygen, 1O2 (1Δg). The solvents are investigated by resorting to the detection of the infra-red luminescence of 1O2 at 1270 nm. Preparative peroxidations of representative substrates are carried out in the most efficient ones. The latter are protic and polar and constitute a simpler alternative to the well suited but more intricate microemulsion systems for the peroxidation of hydrophobic substrates with chemically generated 1O2.
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