光催化
催化作用
氧化还原
空位缺陷
化学
二氧化碳
碳纤维
氧气
化学工程
光化学
材料科学
无机化学
结晶学
有机化学
复合数
工程类
复合材料
作者
Wei Wang,Wanyi Zhang,Chaoyuan Deng,Hua Sheng,Jincai Zhao
标识
DOI:10.1002/anie.202317969
摘要
Photocatalytic conversion of CO2 and H2 O into fuels and oxygen is a highly promising solution for carbon-neutral recycling. Traditionally, researchers have studied CO2 reduction and H2 O oxidation separately, overlooking potential synergistic interplay between these processes. This study introduces an innovative approach, spatial synergy, which encourages synergistic progress by bringing the two half-reactions into atomic proximity. To facilitate this, we developed a defective ZnIn2 S4 -supported single-atom Cu catalyst (Cu-SA/D-ZIS), which demonstrates remarkable catalytic performance with CO2 reduction rates of 112.5 μmol g-1 h-1 and water oxidation rates of 52.3 μmol g-1 h-1 , exhibiting a six-fold enhancement over D-ZIS. The structural characterization results indicated that the trapping effect of vacancy associates on single-atom copper led to the formation of an unsaturated coordination structure, Cu-S3 , consequently giving rise to the CuZn 'VS ⋅⋅VZn " defect complexes. FT-IR studies coupled with theoretical calculations reveal the spatially synergistic CO2 reduction and water oxidation on CuZn 'VS ⋅⋅VZn ", where the breakage of O-H in water oxidation is synchronized with the formation of *COOH, significantly lowering the energy barrier. Notably, this study introduces and, for the first time, substantiates the spatial synergy effect in CO2 reduction and H2 O oxidation through a combination of experimental and theoretical analyses, providing a fresh insight in optimizing photocatalytic system.
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