吡啶
结晶学
铁磁性
发光
八面体
晶体结构
锰
材料科学
单晶
过渡金属
卤化物
顺磁性
分子
化学
无机化学
凝聚态物理
物理
有机化学
冶金
催化作用
光电子学
作者
Chunyang Li,Xianwei Bai,Yongchang Guo,B. S. Zou
出处
期刊:ACS omega
[American Chemical Society]
日期:2019-05-02
卷期号:4 (5): 8039-8045
被引量:43
标识
DOI:10.1021/acsomega.8b03661
摘要
Pure transition-metal compounds seldom produce luminescence because of electron correlation and spin–spin coupling. The Pb-free perovskite materials, C10H12N2MnCl4 and C5H6NMnCl3·H2O, were obtained by using pyridine-implanted manganese chloride lattices. The single-crystal X-ray diffraction indicates their different crystal structures. In C10H12N2MnCl4, MnCl4 cocoordinated with two pyridine molecules forms a lattice composed of independent mononuclear structures with paramagnetic behavior, which shows a clear emission band at 518 nm from the lowest d–d transition of a single Mn(II) ion in the octahedral crystal field. In C5H6NMnCl5·H2O crystal, MnCl5·(H2O)x octahedron-cocoordinated with less pyridine molecules than 2 lead to formation arris-share linear chains of Mn-ion octahedra, which give emission band at 620 nm due to the ferromagnetic Mn pair, and ferromagnetism. Pyridine incorporations in the transition-metal halide lattice provide a new channel to modulate the electron correlation and obtain materials with both luminescence and ferromagnetic properties.
科研通智能强力驱动
Strongly Powered by AbleSci AI