Twip公司
腐蚀
材料科学
奥氏体
氧化物
冶金
X射线光电子能谱
氯化物
极化(电化学)
化学
微观结构
化学工程
工程类
物理化学
作者
S. Fajardo,Irene Llorente,José Antonio Jiménez,J. M. Bastidas,David M. Bastidas
标识
DOI:10.1016/j.corsci.2019.04.026
摘要
Corrosion of TWIP austenitic steels Fe-Mn-3Al-3Si was studied using polarization curves, EIS tests and XPS. Results indicated that increased concentrations of Mn were detrimental to its corrosion resistance. XPS study revealed that pseudo-protective oxide layer was composed of FeO, Fe2O3, FeOOH, Al2O3, MnO and MnO2. Enrichment of Mn oxides in the outermost oxide layer was found as Mn increased in the TWIP steel bulk along with a decrease in Fe oxides. The increased corrosion susceptibility exhibited with the concentration of Mn in the alloys was associated with the greater contribution of the less protective Mn oxide in the surface film.
科研通智能强力驱动
Strongly Powered by AbleSci AI