检出限
氨
电极
电化学
合金
化学
铂金
纳米颗粒
化学工程
催化作用
无机化学
纳米技术
分析化学(期刊)
材料科学
色谱法
物理化学
工程类
有机化学
生物化学
作者
Guanda Wang,Jie Gao,Bangning Sun,Dong He,Chun Zhao,Hui Suo
标识
DOI:10.1016/j.jelechem.2022.116721
摘要
The alloying of Pt with transition metals is significant in boosting the performance of Pt-based electrochemical sensors. In this paper, Platinum and copper alloy nanoparticles (PtCu NPs) were in-situ loaded on carbon cloth (CC) by electrochemical deposition to obtain a self-supported electrode (PtCu-CC) for electrochemical detection of ammonia. The alloying of Pt and Cu reduced the crystal lattice spacing of Pt and improved the catalytic performance of ammonia. Therefore, the PtCu-CC electrode displayed visibly enhanced ammonia detection performance compared with the Pt-CC electrode and commercial Pt electrode. The linear range for ammonia determination was from 0.5 to 40 and 40–500 μM, and the sensitivity of the Pt7Cu1-CC sensor was 9.5 μA μM−1 cm−2 and 0.778 mA lg μM−1 cm−2, respectively. The detection limit was 8.6 ± 0.32 nM, and the quantification limit was 28.67 ± 0.73 nM. The developed sensor shows good anti-interference capability, reproducibility and stability; in addition, it exhibited good capacity in the actual water sample test. PtCu alloy nanoparticles were applied to ammonia detection in water, which may broaden the ways of ammonia detection in water.
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