纤维素
超亲水性
自愈水凝胶
乳状液
材料科学
化学工程
细菌纤维素
肿胀 的
色谱法
复合材料
润湿
化学
高分子化学
工程类
作者
Mengling Wang,Zhaoqian Li,An Chen,Qiang Tian,Xun Liu,Qing Luo,Chonghua Pei
出处
期刊:Cellulose
[Springer Nature]
日期:2022-06-06
卷期号:29 (11): 5979-5990
被引量:3
标识
DOI:10.1007/s10570-022-04642-2
摘要
Cellulose hydrogels are potential candidates to remove water from oil–water emulsions. However, their practical application has been limited by complex processing procedures and low separation rates limited by high water holding rates. Therefore, in this work, natural bacterial cellulose (BC) hydrogel with the characteristics of underwater superoleophobicity/underoil superhydrophilicity is introduced to remove water from oil-in-water and water-in-oil emulsions. Also, the influence of the treatment process of BC hydrogel on the separation rate was studied. The results showed that the separation rate of treated BC hydrogel was significantly higher than that of the original BC hydrogel, and the maximum separation flux could reach 180,000 ± 50 Lm−3 h−1 MPa−1. The mechanism has been investigated by the small-angle X-ray scattering and atomic force microscope, which was attributed to the decrease of the capability to confine water caused by the bundling of cellulose microfibrils during freezing or drying. The work might provide an alternative approach for improving the separation rate of cellulose materials for oil/water separation.
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