Electrolytic Recovery of Indium from Copper Indium Gallium Selenide Photovoltaic Panels: Preliminary Investigation of Process Parameters

The European Green Deal emphasizes the development of renewable energy sources to combat climate change. However, as photovoltaic expansion accelerates, so does the potential for increased waste, necessitating effective material recycling strategies. Indium, a scarce and valuable element crucial to the production of photovoltaic panels, underscores the necessity for efficient recycling practices to reduce reliance on virgin resources. In a recent laboratory analysis, a CIGS photovoltaic panel underwent a series of processes including crushing, grinding, and homogenization. The concentration of indium, vital for recycling, was meticulously analyzed using ICP-MS and validated through microscopic and composition analyses. Subsequent extraction utilizing 3 M HCl and H2O2, followed by electrolysis, yielded a remarkable up to 52% indium recovery within a 48-h timeframe. Importantly, the study encompassed both averaged panel samples and samples from the absorbing layer, emphasizing the comprehensive approach required for efficient recycling. This underscores the critical importance of optimizing recycling processes to mitigate the environmental impact associated with the disposal of photovoltaic panels. By maximizing indium recovery, not only are environmental impacts reduced, but the long-term sustainability of renewable energy technologies is also ensured. This highlights the interconnectedness of recycling practices with the broader goals of achieving a circular economy and securing the viability of renewable energy systems in the fight against climate change.