材料科学
亚麻籽油
涂层
聚氨酯
钴
聚合物
固化(化学)
复合材料
腐蚀
化学工程
冶金
有机化学
工程类
化学
作者
Dan Li,Limin Qing,Menru Li,Houde Cheng,Yang Guiyan,Qiang Fu,Youyi Sun
标识
DOI:10.1016/j.porgcoat.2022.106776
摘要
A new microcapsule was prepared by a facile emulsions process for improving the self-repairing speed of anti-corrosive polymer coating. The microcapsule is based on the cobalt octoate/linseed oil and GO nanosheets, which acts as core and shell. The new microcapsule in polyurethane coating provided the ultra-fast self-repairing speed (ca.5.0 min). The result was attributed to synergistic catalytic curing reaction of linseed oil in presence of cobalt octoate and O 2 . Furthermore, it also improved their anti-corrosion properties due to the good barrier of the GO nanosheets. The work confirms the formation of anti-corrosive polymer coating with ultra-fast self-repairing performance for various applications. • A new rapid self-repairing anti-corrosive coating was developed. • A new microcapsule was synthesized based on catalytic O 2 curing reaction. • It showed ultra-rapid self-repairing of 5 min for anti-corrosive performance.
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