胶束
化学
部分
三萜
甲醇
放松(心理学)
脱氧胆酸
水动力半径
质子核磁共振
有机化学
胆汁酸
水溶液
生物化学
病理
替代医学
社会心理学
医学
心理学
作者
С. С. Петрова,Anna A. Schlotgauer,Alexander I. Kruppa,Tatyana V. Leshina
标识
DOI:10.1515/zpch-2016-0845
摘要
Abstract The use of various NMR techniques allows to demonstrate the aggregation processes of β-glycyrrhizic acid (GA) in water/methanol (4:1, v:v) mixture with solution pH≤5. The micelle formation was monitored by measuring T 2 relaxation and diffusion of GA. The model of gelation from micelles was suggested. It was shown that NMR chemical shifts of the protons of GA glucuronic moiety are sensitive to solution pH and not sensitive to GA concentration changes. At the same time the protons of triterpene moiety are sensitive to the nearest environment during the GA aggregation, and micelles are formed by hydrophobic interaction between the triterpene moieties of GA.
科研通智能强力驱动
Strongly Powered by AbleSci AI