Kagome superconductors AV3Sb5 (A = K, Rb, and Cs) have attracted considerable\nattention due to their intriguing combination of unique electron correlations\nand nontrivial band topology. The interplay of these fundamental aspects gives\nrise to a diverse array of exotic electronic phenomena, including\nsuperconductivity and charge density wave (CDW) states. In this review, we\npresent recent advancements in the study of the electronic band structure of\nAV3Sb5 using angle-resolved photoemission spectroscopy (ARPES), including the\nidentification of the multiple van Hove singularities near the Fermi level and\ntheir close relationship with the CDW transition, spectroscopic features\nrelated to CDW-induced symmetry breakings, as well as direct observations of\nnodeless superconducting gaps and moderate electron-phonon couplings through\nultrahigh-resolution ARPES, providing critical insights into the origins of CDW\norder and electron pairing symmetry. By synthesizing these key ARPES findings,\nthis review aims to deepen our understanding of kagome-related physics.\n