超级电容器
材料科学
纳米片
电极
介孔材料
锂(药物)
电解质
透射电子显微镜
电流密度
扫描电子显微镜
纳米技术
化学工程
电容
电化学
复合材料
化学
催化作用
医学
物理
工程类
内分泌学
量子力学
物理化学
生物化学
作者
Anjon Kumar Mondal,Dawei Su,Shuangqiang Chen,Katja Kretschmer,Xiuqiang Xie,Hyo‐Jun Ahn,Guoxiu Wang
出处
期刊:ChemPhysChem
[Wiley]
日期:2014-11-04
卷期号:16 (1): 169-175
被引量:123
标识
DOI:10.1002/cphc.201402654
摘要
Abstract A facile microwave method was employed to synthesize NiCo 2 O 4 nanosheets as electrode materials for lithium‐ion batteries and supercapacitors. The structure and morphology of the materials were characterized by X‐ray diffraction, field‐emission scanning electron microscopy, transmission electron microscopy and Brunauer–Emmett–Teller methods. Owing to the porous nanosheet structure, the NiCo 2 O 4 electrodes exhibited a high reversible capacity of 891 mA h g −1 at a current density of 100 mA g −1 , good rate capability and stable cycling performance. When used as electrode materials for supercapacitors, NiCo 2 O 4 nanosheets demonstrated a specific capacitance of 400 F g −1 at a current density of 20 A g −1 and superior cycling stability over 5000 cycles. The excellent electrochemical performance could be ascribed to the thin porous structure of the nanosheets, which provides a high specific surface area to increase the electrode–electrolyte contact area and facilitate rapid ion transport.
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