化学
乳酸乙酯
催化作用
气相
相(物质)
氧化物
无机化学
有机化学
热力学
物理
作者
Shigeru Sugiyama,Naoya Shigemoto,Naoki Masaoka,Souichi Suetoh,Hideaki Kawami,K. Miyaura,Hiromu Hayashi
摘要
Abstract Oxidation of ethyl lactate to pyruvate was carried out in vapor-phase over various oxides. MoO3 showed a higher selectivity than that of the other single oxide examined. Binary oxides containing molybdenum such as Fe2O3–MoO3 and TeO2–MoO3 showed high selectivities to pyruvate over 90% at 300 °C with high lactate conversion over 75%. The maximum activity on SnO2–MoO3 was observed at a low temperature of 250 °C.
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