三氟甲基
酰亚胺
晶体结构
偶极子
层状结构
固态
化学
结晶学
材料科学
物理化学
有机化学
烷基
作者
Hikaru Nakayama,Jun‐ichi Nishida,Noriyuki Takada,Hiroyasu Sato,Yoshiro Yamashita
摘要
A series of asymmetric N-phenyl imides with trifluoromethyl and pentafluorosulfanyl substituents at the terminal phenyl position have been prepared. They are colorless both in solution and the solid state, and they show blue emission in the solid state. X-ray crystal structure analysis of trifluoromethyl and pentafluorosulfanyl substituted derivatives revealed highly ordered noncentrosymmetric molecular arrangements with large net-dipole moments related to the piezoelectric behavior. XRD measurements of the powders afforded intense sharp reflection peaks, indicating formation of the lamellar ordering. By grinding with a spatula, their solids showed vivid blue triboluminescence.
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