化学
钋
溶解度
离子液体
无机化学
硫氰酸盐
氯化物
傅里叶变换红外光谱
磺酸盐
衰减全反射
红外光谱学
有机化学
钠
化学工程
工程类
催化作用
作者
Ana B. Pereiro,João M. M. Araújo,Filipe S. Oliveira,José M. S. S. Esperança,José N. Canongia Lopes,Isabel M. Marrucho,Luís Paulo N. Rebelo
标识
DOI:10.1016/j.jct.2012.06.007
摘要
The solubility of different conventional salts in several room-temperature ionic liquids – containing ammonium, phosphonium or imidazolium cations combined with acetate, sulfate, sulfonate, thiocyanate, chloride, tetracyano-borate, tris(pentafluoroethyl)trifluoro-phosphate, l-lactate, bis(trifluoromethylsulfonyl)imide or trifluoromethylsulfonate anions – were screened using a visual detection method. The most promising mixtures were then re-measured using an ATR–FTIR (Attenuated Total Reflection Fourier Transform Infra Red) spectroscopy technique in order to accurately and quantitatively determine the corresponding solubility at 298.15 K.
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