电解质
碳酸乙烯酯
阳极
法拉第效率
化学工程
材料科学
离子电导率
碳酸二甲酯
电导率
分解
锂(药物)
无机化学
化学
电极
有机化学
物理化学
工程类
内分泌学
医学
甲醇
作者
Masakazu Haruta,Takashi Okubo,Yuta Masuo,Shuhei Yoshida,Akira Tomita,Toshihide Takenaka,Takayuki Doi,Masaaki Inaba
标识
DOI:10.1016/j.electacta.2016.12.071
摘要
Silicon nanoflake powder (Si LeafPowder®, Si-LP) used as an anode material for lithium-ion batteries has demonstrated superior cycle performance at 30 °C in an ethylene-carbonate-based electrolyte solution because its characteristic thin-film-based structure resists pulverization. However, capacity fading was accelerated at 60 °C owing to enhanced decomposition of the electrolyte solution and growth of a solid electrolyte interface (SEI), which leads to loss of the electronic contact between Si-LP particles. The SEI-forming additives vinylene carbonate (VC), fluoroethylene carbonate (FEC), and difluoroethylene carbonate improved the capacity retention and Coulombic efficiency at 30 °C. Although VC is the most effective additive at 60 °C, the discharge capacity was decreased dramatically at −5 °C owing to poor ionic and electronic conductivity of the SEI layer formed from the VC-added electrolyte solution. The added FEC produced better performance in a wide temperature range of −5 to 60 °C because the SEI layer formed in the FEC-added electrolyte solution had higher ionic and electronic conductivity than that formed from VC, even at −5 °C. To obtain Si anodes with high discharge capacity and long cycle life, an appropriate choice of SEI-forming additive taking into account the operating temperature is important.
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