Ionic Polyimine‐Based Composite Membrane with Inductive and Complexation Synergistic Effects for Sensitive and On‐Site Fluorescent Detection of Volatile Iodine

Abstract Along with the development of nuclear power, concerns about radioactive emissions and the potential for nuclear leakage have been widely raised, particularly of harmful iodine isotopes. However, as a significant component of nuclear air waste, the enrichment and detection of air‐dispersed gaseous iodine remain a challenge. In this work, it is focused on developing an attraction‐immobilization‐detection strategy‐based fluorescence method for the on‐site detection of volatile iodine, by employing a photoluminescent ionic polyimine network‐polyvinylpyrrolidone (IPIN‐PVP) composite membrane. This strategy synergizes ion‐induced dipole interactions from IPIN and complexation effects from PVP, allowing effective iodine enrichment and immobilization. As a result, the optimized IPIN‐PVP membrane exhibits rapid response times of 5 s and a low detection limit of 4.087 × 10 −8 m for gaseous iodine. It also introduces a portable handheld detection device that utilizes the composite membrane, offering a practical solution for real‐time on‐site detection of volatile iodine. This innovation enhances nuclear safety measures and disaster management by providing rapid and reliable iodine detection capabilities.