Calibration models of quantitative analysis of the content of peanut oil in blended edible oil were built using partial-least-square(PLS) regression and other methods.Near infrared diffuse reflectance spectra of the calibration sample set were collected over 4 000 cm-1~10 000 cm-1 spectral region.Calibration model was established with PLS after the spectra were pretreated with first derivative and validated with leave-one-out cross validation method.The correlation coefficient was 0.99961 and the RMSEC was 0.830 % for the model.Among different spectra pretreatment methods,the first derivative was the best one.The comparison of the calibration models built with different methods showed that the PLS was the optimal one.