Reaction Pathways of Standard and Fast Selective Catalytic Reduction over Cu-SSZ-39

Cu-SSZ-39 exhibits excellent hydrothermal stability and is expected to be used for NO_x purification in diesel vehicles. In this work, the selective catalytic reduction (SCR) activities in the presence or absence of NO₂ were tested over Cu-SSZ-39 catalysts with different Cu contents. The results showed that the NO_x conversion of Cu-SSZ-39 was improved by NO₂ when NO₂/NO_x = 0.5, especially for the catalysts with low Cu loadings. The kinetic studies showed two kinetic regimes for fast SCR from 150 to 220 °C due to a change in the rate-controlling mechanism. The activity test and diffuse reflectance infrared Fourier transform spectra demonstrated that the reduction of NO mainly occurred on the Cu species in the absence of feed NO₂, and when NO₂/NO = 1, NO could react with NH₄NO₃ on the Brønsted acid sites in addition to undergoing reduction on Cu species. Thus, NO₂ can promote the SCR reaction over Cu-SSZ-39 by facilitating the formation of surface nitrate species.