超分子化学
分子内力
芳基
热稳定性
分子
硅烷化
纳米技术
组合化学
数码产品
催化作用
材料科学
化学
分子电子学
有机化学
烷基
物理化学
作者
Shen Xu,Huanhuan Li,Yuting Tang,Runfeng Chen,Xiaoji Xie,Xin‐Hui Zhou,Guichuan Xing,Wei Huang
摘要
An efficient metal-free radical-catalyzed intramolecular silylation method has been developed for the preparation of all-aryl phenazasilines, which can be hardly synthesized by traditional synthetic methods. The easily prepared aromatic and rigid phenazasiline exhibits excellent solubility, high thermal stability, and good optoelectronic properties, which are highly attractive for optical and electronic applications in organic electronics. These advances, in the preparation of all-aryl phenazasilines, offer exciting opportunities for sophisticated molecular design and efficient synthesis of optoelectronic molecules based on the phenazasiline.
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