胶粘剂
制作
砂纸
涂层
润湿
材料科学
硅烷
超疏水涂料
疏水二氧化硅
接触角
磨损(机械)
纳米颗粒
化学工程
水解
表面改性
复合材料
纳米技术
图层(电子)
有机化学
化学
病理
工程类
替代医学
医学
作者
Tingting Ren,Biao Yuan,Gongwen Tang,Ming Zhao,Yang Yang,Yan Zhang,Liang Ma,Xin Huang
标识
DOI:10.1002/slct.202202426
摘要
Abstract Eco‐friendly, easy, fast and scalable strategies for robust superhydrophobic coatings are of great significance for industrial application. Herein, a robust fluorine‐free superhydrophobic coating is prepared via spraying the mixed suspension which consist of silica nanoparticles and hydrophobic acid‐catalyzed silica sol. The adhesive which is synthesized through hydrolyzation and condensation of silane precursors (TEOS, MTMS, HDTMS) shows good compatibility with silica nanoparticles. When the mass ratio of SiO 2 /adhesive was 0.025 : 1, the prepared coating exhibited good non‐wettability with a WCA of 164° and a RA of 2°. Moreover, due to the hydrophobic acid‐catalyzed silica sol which bonds silica nanoparticles together, the coatings also demonstrate well mechanical robustness. After 60 g sand impacted on the surface of as‐prepared coating from a height of 1 m, the surface still showed superhydrophobicity with a WCA of 152° and a RA of 6°. And the as‐prepared coating could endure the sandpaper abrasion for 80 cm. Furthermore, the adhesion of as‐prepared coatings to substrates can reach the highest 5 A level. The current work provides an easy and promising approach to meet the challenges in practical applications simultaneously posed by the fluorine‐free, low‐cost, mechanical robustness as well as large‐scale preparation of silica‐based superhydrophobic coatings.
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