芘
材料科学
组合化学
吸收(声学)
非线性光学
共轭体系
化学
纳米技术
有机化学
非线性系统
聚合物
物理
复合材料
量子力学
作者
Shuchen Tian,Hui Cao,Zhou Yang,Yuzhen Zhao,Wanli He,Hong Gao
出处
期刊:Pigment & Resin Technology
[Emerald (MCB UP)]
日期:2021-10-18
卷期号:52 (1): 1-6
被引量:2
标识
DOI:10.1108/prt-03-2021-0029
摘要
Purpose Currently, conjugated nonlinear optical (NLO) materials suffer from the drawbacks of complex manufacturing process and high cost. To further study the NLO materials with cost-effective, it is necessary to prepare new NLO materials with satisfactory performance. Design/methodology/approach Pyrene derivatives with good third-order NLO properties were synthesized by combining pyrene compounds with TCNE, TCNQ, F4-TCNQ and other molecular systems by clicking chemical method. Findings The pyrene derivatives were characterized by ultraviolet spectrum and Z-scan. The charge-transfer of the D-p-A structures plays a key role in the absorption peak shifts. And the third-order nonlinear absorption of the products revealed good third-order NLO susceptibilities. Research limitations/implications The synthesis technology of pyrene derivatives is not mature enough and is in the preliminary exploration stage. So, the authors produced a relatively small number of samples and did not conduct a very comprehensive test. Practical implications This novel pyrene derivative is suggestive and can promote the exploration and development of the third-order nonlinear materials. Originality/value Four new pyrene derivatives were synthesized by selecting new molecular systems. Because of its good chemical properties and stable properties, it can be a reference for the development of third-order nonlinear materials in the future.
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