Recent Development of Ir- and Ru-Based Electrocatalysts for Acidic Oxygen Evolution Reaction

Proton exchange membrane (PEM) water electrolyzers are one type of the most promising technologies for efficient, nonpolluting and sustainable production of high-purity hydrogen. The anode catalysts account for a very large fraction of cost in PEM water electrolyzer and also determine the lifetime of the electrolyzer. To date, Ir- and Ru-based materials are types of promising catalysts for the acidic oxygen evolution reaction (OER), but they still face challenges of high cost or low stability. Hence, exploring low Ir and stable Ru-based electrocatalysts for acidic OER attracts extensive research interest in recent years. Owing to these great research efforts, significant developments have been achieved in this field. In this review, the developments in the field of Ir- and Ru-based electrocatalysts for acidic OER are comprehensively described. The possible OER mechanisms are first presented, followed by the introduction of the criteria for evaluation of the OER electrocatalysts. The development of Ir- and Ru-based OER electrocatalysts are then elucidated according to the strategies utilized to tune the catalytic performances. Lastly, possible future research in this burgeoning field is discussed.