材料科学
阳极
电解质
电池(电)
阴极
电化学
锂(药物)
溶解
化学工程
杂质
枝晶(数学)
电极
纳米技术
储能
氧化还原
金属锂
冶金
电气工程
物理化学
热力学
医学
功率(物理)
化学
物理
有机化学
内分泌学
工程类
几何学
数学
作者
Yong Guo,Siyuan Pan,Xuerui Yi,Sijia Chi,Xunjie Yin,Chuannan Geng,Qiuxiang Yin,Qian Zhan,Zhiyang Zhao,Fengmin Jin,Hui Fang,Yan‐Bing He,Feiyu Kang,Shichao Wu,Quan‐Hong Yang
标识
DOI:10.1002/adma.202308493
摘要
Li-stuffed battery materials intrinsically have surface impurities, typically Li2CO3, which introduce severe kinetic barriers and electrochemical decay for a cycling battery. For energy-dense solid-state lithium batteries (SSLBs), mitigating detrimental Li2CO3 from both cathode and electrolyte materials is required, while the direct removal approaches hardly avoid Li2CO3 regeneration. Here, a decarbonization-fluorination strategy to construct ultrastable LiF-rich interphases throughout the SSLBs by in situ reacting Li2CO3 with LiPF6 at 60 °C is reported. The fluorination of all interfaces effectively suppresses parasitic reactions while substantially reducing the interface resistance, producing a dendrite-free Li anode with an impressive cycling stability of up to 7000 h. Particularly, transition metal dissolution associated with gas evolution in the cathodes is remarkably reduced, leading to notable improvements in battery rate capability and cyclability at a high voltage of 4.5 V. This all-in-one approach propels the development of SSLBs by overcoming the limitations associated with surface impurities and interfacial challenges.
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