异质结
X射线光电子能谱
材料科学
光催化
电子转移
复合数
金属
化学工程
光电子学
纳米技术
催化作用
光化学
化学
复合材料
有机化学
冶金
工程类
作者
Qiaoqiao Mu,Zhu Wang,Xian Li,Chufeng Zhang,Yanhui Su,Yuebin Lian,Pengwei Qi,Zhao Deng,Duo Zhang,Shuao Wang,Xing Zhu,Yang Peng
标识
DOI:10.1016/j.apcatb.2019.118144
摘要
In this work, composite thin films comprising the 2D/2D MOF/rGO heterostructures assembled via Coulomb interaction are employed as the cocatalyst for photocatalytic CO2 reduction for the first time. The electrostatic charge transfer and the strong π-π interaction induced in the heterostructure effectively modulate the electronic structure of the metal centers in the conductive 2D MOF (Ni3HITP2), evidenced by Zeta Potentials, HR-TEM, XPS and XANES. The best thin-film catalyst with an optimal MOF/rGO ratio demonstrates a high CO evolution rate of 3.8 × 104 μmol h−1 gfilm−1 (0.46 min−1 in TOF) and a good selectivity of 91.74%, synergically contributed by the improved photoelectron harvesting on the rGO scaffold, the efficient charge transportation/transfer within the conductive and intimate 2D heterostructure, the coherent energy flow owing to aligned energy levels, and the enriched electron density at the isolated Ni-N4 sites boosted by electrostatic charge transfer.
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