催化作用
联氨(抗抑郁剂)
化学
铜
氧化还原
锰
无机化学
氧气
反应速率
同种类的
速率方程
杂质
动力学
有机化学
热力学
色谱法
量子力学
物理
作者
H. Gaunt,E. A. M. Wetton
出处
期刊:Journal of applied chemistry
[Wiley]
日期:1966-06-01
卷期号:16 (6): 171-176
被引量:19
标识
DOI:10.1002/jctb.5010160602
摘要
Abstract Studies of the reaction between hydrazine and oxygen at 25° and 70° in alkaline solution have shown that the observed rate is due to catalysis by traces of impurities. It has been found that copper(II) and manganese (II) are the most active catalysts, and, under certain conditions, the copper(II)‐catalysed reaction appears to be homogeneous. Evidence is presented that catalysis occurs by redox reactions. The copper(II)‐catalysed reaction has been studied in some detail, but only the earlier stages fit a simple kinetic equation.
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