电致变色
材料科学
计时安培法
循环伏安法
三氧化钨
五氧化二铁
薄膜
碳酸丙烯酯
钒
氧化锡
化学工程
钨酸盐
无机化学
电化学
氧化钒
钨酸钠
电致变色装置
钨
氧化物
电极
化学
纳米技术
冶金
物理化学
工程类
作者
Chetan A. Patil,N.L. Tarwal,Pravin Jadhav,Pravin S. Shinde,H.P. Deshmukh,M. M. Karanjkar,A.V. Moholkar,Myeng Gil Gang,J.H. Kim,Pramod S. Patil
标识
DOI:10.1016/j.cap.2013.12.014
摘要
Vanadium pentoxide (V2O5) mixed tungsten trioxide (WO3) thin films have been synthesized by a novel pulsed spray pyrolysis technique (PSPT) on glass and fluorine doped tin oxide (FTO) coated glass substrates at 400 °C. Aqueous solutions of equimolar vanadium chloride and ammonium tungstate were mixed in volume proportions (5%, 10% and 15%) for the deposition of V2O5–WO3 thin films. The structural, morphological, optical and electrochemical properties of V2O5–WO3 thin films were investigated by FT-IR, XRD, SEM, cyclic voltammetry, chronoamperometry and chronocoulometry techniques. The results showed that the electrochemical properties of V2O5 were altered by mixing WO3. All the films exhibited cathodic electrochromism in lithium containing electrolyte (0.5 M LiClO4 + propylene carbonate (PC)). Maximum coloration efficiency (CE) of about 49 cm2 C−1 was observed for the V2O5 film mixed with 15% WO3. The electrochemical stability of the sample was examined and it was found to be stable up to 1000 cycles.
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